If I deposit btc to my muun wallet via on chain can I spend it via lightning?
yes but you might get fucked on the fee via lightning with muun. They love to overcharge lightning tx fees. Better option is cctip/cwallet. Deposit to the btc address they give you, await confirmations, then you can swap instantly to 'sats' and send to any invoice. They do not support lnurl though.
Another option is fixedfloat. If you're in the US just use a vpn to spoof your location. They offer a swap from on chain to lightning for a small fee of 0.5% and minimums of only $1 usd.
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